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1. Introduction to Electrochemical Cells
- Electrochemical cells convert chemical energy into electrical energy or vice versa.
- They are classified into two types: Galvanic cells (voltaic cells) and electrolytic cells.
- In both types, redox reactions occur, involving electron transfer.
2.
1. Introduction to Redox Reactions
- Redox reactions involve both oxidation (loss of electrons) and reduction (gain of electrons).
- The term oxidation originally referred to the addition of oxygen, while reduction referred to the removal of oxygen.
- Modern definitions are based on the transfer of electrons.
2.
1. Overview of Le Chatelier’s Principle
- Le Chatelier’s Principle states that when a system at equilibrium is subjected to a change in concentration, pressure, or temperature, the system adjusts itself to minimize the effect of the disturbance and restore a new equilibrium.
- This principle helps predict the direction in which the equilibrium will shift in response to external changes.
2.
1. Law of Mass Action
- The Law of Mass Action states that the rate of a chemical reaction is directly proportional to the product of the concentrations of the reactants raised to their respective stoichiometric coefficients.
- For a reversible reaction: aA + bB ⇌ cC + dD, the equilibrium expression is: