Thermodynamics

1. Law of Mass Action

  1. The Law of Mass Action states that the rate of a chemical reaction is directly proportional to the product of the concentrations of the reactants raised to their respective stoichiometric coefficients.
  2. For a reversible reaction: aA + bB ⇌ cC + dD, the equilibrium expression is: 

1. Zeroth Law of Thermodynamics

  1. The Zeroth Law establishes the concept of thermal equilibrium.
  2. If two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
  3. It provides the foundation for the measurement of temperature.
  4. Temperature is a property that determines whether systems are in thermal equilibrium.
  5. This law is fundamental to the design of thermometers.

2.

System

  1. A system refers to the part of the universe under study or observation.
  2. The boundaries of a system separate it from the surroundings.
  3. Systems are classified based on the type of exchanges that occur across their boundaries.
  4. Examples of systems include a gas in a cylinder, a chemical reaction in a flask, or a biological cell.
  5. A system is defined in terms of its properties such as temperature, pressure, volume, and composition.

Surroundings

  1. The surroundings