Skip to main content
1. Law of Mass Action
- The Law of Mass Action states that the rate of a chemical reaction is directly proportional to the product of the concentrations of the reactants raised to their respective stoichiometric coefficients.
- For a reversible reaction: aA + bB ⇌ cC + dD, the equilibrium expression is:
1. Zeroth Law of Thermodynamics
- The Zeroth Law establishes the concept of thermal equilibrium.
- If two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
- It provides the foundation for the measurement of temperature.
- Temperature is a property that determines whether systems are in thermal equilibrium.
- This law is fundamental to the design of thermometers.
2.
System
- A system refers to the part of the universe under study or observation.
- The boundaries of a system separate it from the surroundings.
- Systems are classified based on the type of exchanges that occur across their boundaries.
- Examples of systems include a gas in a cylinder, a chemical reaction in a flask, or a biological cell.
- A system is defined in terms of its properties such as temperature, pressure, volume, and composition.
Surroundings
- The surroundings