Skip to main content
VSEPR Theory
- VSEPR Theory stands for Valence Shell Electron Pair Repulsion Theory.
- It is used to predict the shape of molecules based on electron pair repulsion.
- The theory states that electron pairs around a central atom arrange themselves to minimize repulsion.
- Both bonding pairs and lone pairs of electrons influence molecular geometry.
- Lone pairs occupy more space than bonding pairs due to greater repulsion.
- The molecu
Valence Bond Theory (VBT)
- Valence Bond Theory (VBT) explains the formation of chemical bonds through the overlap of atomic orbitals.
- In VBT, atoms combine by overlapping their valence orbitals to form bonds.
- The overlapping orbitals contain unpaired electrons, which pair up to form a covalent bond.
- Bond strength depends on the extent of overlap; greater overlap results in stronger bonds.
- VBT distinguishes between sigma (σ) and pi (π) bonds based
Electronegativity
- Electronegativity is the ability of an atom to attract shared electrons in a chemical bond.
- Measured on the Pauling scale, where fluorine has the highest value (4.0).
- Electronegativity increases across a period from left to right due to increasing nuclear charge and a smaller atomic radius.
- Electronegativity decreases down a group as atomic size increases, reducing the pull on shared electrons.
- Non-metals like oxygen, nitrogen, and fluor
Atomic and Ionic Radii
- The atomic radius is the distance from the nucleus to the outermost shell of an atom.
- Atomic radius decreases across a period due to increased nuclear charge, which pulls electrons closer to the nucleus.
- Atomic radius increases down a group because of the addition of new electron shells.
- Cations (positively charged ions) have smaller radii than their parent atoms due to the loss of electrons and reduced electron-electron re
Mendeleev’s Periodic Table
- Proposed by Dmitri Mendeleev in 1869.
- Based on the periodic recurrence of properties of elements when arranged in order of increasing atomic mass.
- Contained 63 known elements at the time.
- Mendeleev organized elements into rows and columns to form the periodic table.
- He left gaps in the table for undiscovered elements and predicted their properties accurately, such as gallium (eka-aluminum) and g
Isotopes
- Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons.
- As a result, isotopes have the same atomic number but different mass numbers.
- Examples of isotopes include:
- Hydrogen: Protium (¹H), Deuterium (²H), Tritium (³H).
- Carbon: Carbon-12 (¹²C), Carbon-13 (¹³C), Carbon-14 (¹⁴C).
- Isotopes exhibit identical chemical properties but different
Quantum Numbers
- Quantum numbers describe the state and position of an electron in an atom.
- There are four quantum numbers:
- Principal Quantum Number (n): Indicates the main energy level or shell of the electron.
- Azimuthal Quantum Number (l): Defines the subshell and shape of the orbital (0 for s, 1 for p, 2 for d, 3 for f).
- Magnetic Quantum Number (ml): Specifies the orientation of the orbital in space.
- S
Bohr's Model of the Atom
- Proposed by Niels Bohr in 1913.
- Based on Rutherford’s model and Planck's quantum theory.
- Electrons revolve around the nucleus in fixed circular paths called orbits or energy levels.
- These energy levels are represented as n = 1, 2, 3, ... (principal quantum numbers).
- Each orbit has a fixed amount of energy, and electrons do not radiate energy while in a stable orbit.
- Electrons can transition betwee
Dalton's Atomic Theory
- Proposed by John Dalton in 1803.
- It was the first scientific theory to describe the nature of matter in terms of atoms.
- Matter is made up of small, indivisible particles called atoms.
- Atoms of a given element are identical in size, mass, and other properties.
- Atoms of different elements differ in size, mass, and other properties.
- Atoms cannot be created, divided, or destroyed during chemical reactions.
- Atoms combine in simple whole-number ratios to form
Protons
- The proton is a positively charged particle with a relative charge of +1.
- The atomic number is determined by the number of protons in the nucleus.
- Protons were discovered by Ernest Rutherford in 1917.
- The charge of a proton is +1.6 × 10⁻¹⁹ coulombs.
- Protons are part of the nucleus and contribute to the atom's mass.
Neutrons
- The neutron has no charge, making it neutral